Here are the steps for Open Multiple G-talk Accounts on Single Machine with Different Login Ids:
1) Create a G-talk shortcut on the desktop (If not available already).
2) Right Click on the shortcut and click on properties.
3) In the end of the Target field, you have to write “Nomutex”. Refer to the below snapshot.
1) Create a G-talk shortcut on the desktop (If not available already).
2) Right Click on the shortcut and click on properties.
3) In the end of the Target field, you have to write “Nomutex”. Refer to the below snapshot.

4) Now Click on Apply and OK, and open your G-talk two times and enter two different G-mail Id's and you will have two different chat windows for you G-talk account.
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